banner



Home  ›  Lithium And Sulfur Ionic Compound

Lithium And Sulfur Ionic Compound

Written By Wednesday, November 2, 2022 Add Comment Edit

Abstract

The lithium-sulfur battery has high theoretical specific capacity (1675 mAh g−ane) and energy density (2567 Wh kg−1), and is considered to be i of the near promising high-energy–density storage battery systems. However, the polysulfides produced during the charging and discharging process of the lithium-sulfur battery will migrate dorsum and forth betwixt the positive and negative electrodes of the battery causing a "shuttle consequence," which leads to the decline of the battery's cycle stability and reduction of the utilization rate of agile substances. Transition metal compounds are mutual materials and have always played an active role in the capture and catalysis of polysulfides. This paper reviews the recent progress of enquiry on modifying cathode materials by introducing transition element compounds into lithium-sulfur battery and discusses the time to come development.

References

  1. Yuan West, Qiu ZQ, Wang C, Yuan YH, Yang Y, Zhang XQ, Ye YT, Tang Y (2020) Pattern and interface optimization of a sandwich-structured cathode for lithium-sulfur batteries. Chem Eng J 381:122648

    Article  CAS  Google Scholar

  2. Dong MX, Wang ZX, Li XH, Guo HJ, Wang JX, Yan GC (2020) Vital effect of sufficient vulcanization on the backdrop of Ni-Co-Due south/graphene composites for supercapacitor. Chem Eng Sci 221:115709

    Article  CAS  Google Scholar

  3. Yk Eleven, Angulakshmi Due north, Zhang Past, Tian XH, Tang ZH, Xie PF, Chen GZ, Zhou YK (2020) A Co9Seight microsphere and Northward-doped carbon nanotube composite host fabric for lithium-sulfur batteries. J Alloy Compd 826:154201

    Commodity  Google Scholar

  4. Liu TF, Tong CJ, Wang B, Liu LM, Zhang SQ, Lin Z, Wang DL, Lu J (2019) Trifunctional electrode additive for high agile material content and volumetric lithium-ion electrode densities. Adv Energy Mater nine:1803390

    Commodity  Google Scholar

  5. Liu TF, Zhang YP, Chen C, Lin Z, Zhang SQ, Lu J (2019) Sustainability-inspired jail cell design for a fully recyclable sodium ion battery. Nat Commun ten:1965

    Commodity  PubMed  PubMed Key  Google Scholar

  6. Liu YY, Zhang Y, Liu Y, Zhu J, Ge Z, Li ZJ, Chen YS (2021) Super heating/cooling charge per unit enabled by microwave shock on polymeric graphene foam for high functioning lithium-sulfur batteries. Carbon 173:809–816

    Article  CAS  Google Scholar

  7. Zhao M, Li BQ, Chen X, Xie J, Yuan H, Huang JQ (2020) Redox comediation with organopolysulfides in working lithium-sulfur batteries. Chem six:3297–3311

    Article  CAS  Google Scholar

  8. Gao MY, Tang ZH, Wu MR, Chen JL, Xue YC, Guo XM, Liu YJ, Kong QH, Zhang JH (2021) Self-supporting North, P doped Si/CNTs/CNFs composites with fiber network for loftier-operation lithium-ion batteries. J Alloy Compd 857:157554

    Article  CAS  Google Scholar

  9. Zhao M, Peng YQ, Li BQ, Zhang XQ, Huang JQ (2021) Regulation of carbon distribution to construct high-sulfur-content cathode in lithium-sulfur batteries. J Free energy Chem 56:203–208

    Article  Google Scholar

  10. Zhao M, Chen 10, Li XY, Li BQ, Huang JQ (2021) An organodiselenide comediator to facilitate sulfur redox kinetics in lithium-sulfur batteries. Adv Mater 33:2007298

    Commodity  CAS  Google Scholar

  11. Yang DH, Zhou HY, Liu H, Han BH (2019) Hollow Northward-doped carbon polyhedrons with hierarchically porous shell for confinement of polysulfides in lithium-sulfur batteries. Iscience thirteen:243–253

    Article  CAS  PubMed  PubMed Fundamental  Google Scholar

  12. Vocal ZC, Lu Forty, Hu Q, Ren J, Zhang WQ, Zheng QJ, Lin DM (2019) Synergistic confining polysulfides by rational blueprint a N/P co-doped carbon as sulfur host and functional interlayer for high-operation lithium-sulfur batteries. J Ability Sources 421:23–31

    Article  CAS  Google Scholar

  13. Gueon D, Ju MY, Moon JH (2020) Consummate encapsulation of sulfur through interfacial energy control of sulfur solutions for high-performance Li-Southward batteries. Proc Natl Acad Sci USA 117:12686–12692

    Article  CAS  PubMed  PubMed Central  Google Scholar

  14. Huang X, Qiu TF, Zhang XH, Wang 50, Luo B, Wang LZ (2020) Recent advances of hollow-structured sulfur cathodes for lithium-sulfur batteries. Materials Chemistry Frontiers four:2517–2547

    Commodity  CAS  Google Scholar

  15. Xu YH, Zhang QF, Fan B, Xue B, Chen HJ, Zhang XH, Luo ZK, Wang F, Le Coq D, Calvez L, Ma HL, Fan P (2020) An extremely high rate Li-South bombardment with hybrid electrolyte. J Blend Compd 845:156261

    Article  CAS  Google Scholar

  16. Chen H, Pei A, Lin DC, Xie J, Yang AK, Xu JW, Lin KX, Wang JY, Wang HS, Shi FF, Boyle D, Cui Y (2019) Uniform high ionic conducting lithium sulfide protection layer for stable lithium metal anode. Adv Energy Mater 9:1900858

    Commodity  Google Scholar

  17. Liu FF, Wang LF, Zhang ZW, Shi PC, Feng YZ, Yao Y, Ye SF, Wang HY, Wu XJ, Yu Y (2020) A mixed lithium-ion conductive LitwoS/Li2Se protection layer for stable lithium metal anode. Adv Func Mater thirty:2001607

    Article  CAS  Google Scholar

  18. Liu H, Zeng P, Li YoF YuH, Chen MF, Luo ZhG, Miao CQ, Chen GR, Wang XY (2020) The preparation and performances of lithium sulfide (Li2Due south)-oriented cathode composite via carbothermic reduction. J Alloy Compd 835:155421

    Article  CAS  Google Scholar

  19. Nie B, Zhou CC, Gao MX, He DY, Yao ZH, Liu YF, Shen XY, Wang XW, Pan HG (2019) Bi-structural fibers of carbon nanotube coated with nitrogen/oxygen dual-doped porous carbon layer every bit superior sulfur host for lithium-sulfur batteries. J Alloy Compd 797:1205–1215

    Commodity  CAS  Google Scholar

  20. Qiu WL, Li J, Zhang YG, Kalimuldina One thousand, Bakenov Z (2021) Carbon nanotubes assembled on porous TiO2 matrix doped with Co3O4 as sulfur host for lithium-sulfur batteries. Nanotechnology 32:075403

    Article  CAS  PubMed  Google Scholar

  21. Lee BJ, Kang TH, Lee HY, Samdani JS, Jung YJ, Zhang CF, Yu Z, Xu GL, Cheng L, Byun S, Lee YM, Amine M, Yu JS (2020) Revisiting the office of conductivity and polarity of host materials for long-life lithium-sulfur battery. Adv Energy Mater 10:1903934

    Article  CAS  Google Scholar

  22. Balach J, Linnemann J, Jaumann T, Giebeler 50 (2018) Metallic-based nanostructured materials for advanced lithium-sulfur batteries. J Mater Chem A vi:23903–23903

    Article  CAS  Google Scholar

  23. Wang HQ, Zhang WC, Xu JZ, Guo ZP (2018) Advances in polar materials for lithium-sulfur batteries. Adv Func Mater 28:1707520

    Article  Google Scholar

  24. Dai HH, Wang LM, Zhao Y, Xue JL, Zhou RC, Yu CY, An JN, Zhou JY, Chen Q, Sun GZ, Huang W (2021) Recent advances in molybdenum-based materials for lithium-sulfur batteries. Research 2021:327–356

    Article  Google Scholar

  25. Liu KF, Zhao HB, Ye DX, Zhang JJ (2021) Recent progress in organic polymers-composited sulfur materials equally cathodes for lithium-sulfur battery. Chem Eng J 417:129309

    Article  CAS  Google Scholar

  26. Wang DW, Zeng QC, Zhou GM, Yin LC, Li F, Cheng HM, Gentle IR, Lu GQM (2013) Carbon-sulfur composites for Li-South batteries: status and prospects. Journal of Materials Chemistry A 1:9382–9394

    Article  CAS  Google Scholar

  27. Fang RP, Zhao SY, Sun ZH, Wang DW, Cheng HM, Li F (2017) More reliable lithium-sulfur batteries: status, solutions and prospects. Adv Mater 29:1606823

    Commodity  Google Scholar

  28. Ji PH, Shang B, Peng QM, Hu XB, Wei JW (2018) blastoff-MoOthree spheres as effective polysulfides adsorbent for high sulfur content cathode in lithium-sulfur batteries. J Power Sources 400:572–579

    Article  CAS  Google Scholar

  29. Shao QJ, Guo DC, Wang C, Chen J (2020) Yolk-crush structure MnO2@hollow carbon nanospheres as sulfur host with synergistic encapsulation of polysulfides for improved Li-S batteries. J Alloy Compd 842:155790

    Article  CAS  Google Scholar

  30. Hu J, Wang ZY, Fu Y, Lyu LL, Lu ZG, Zhou LM (2020) In situ associates of MnO2 nanosheets on sulfur-embedded multichannel carbon nanofiber composites equally cathodes for lithium-sulfur batteries. Scientific discipline China-Materials 63:728–738

    Commodity  CAS  Google Scholar

  31. Dong Westward, Meng LQ, Zhao MN, Yang F, Shen D, Hong XD, Tang SW, Sun W, Yang SB (2021) FeiiO3/rGO/CNT composite sulfur hosts with physical and chemic dual-encapsulation for high operation lithium–sulfur batteries. New J Chem 45:21582–21590

    Article  CAS  Google Scholar

  32. Chu XR, Zhang L, Li CL, Zhao ZK, Liu Q, Xie CX, Wu BR, Mu DB (2021) CNTs@S cathode modified with a bulwark layer of TiO2 decorated reduced graphene oxide for lithium-sulfur batteries. Ionics 27:2387–2395

    Article  CAS  Google Scholar

  33. Zhang SJ, Li C, Zhang X, Sunday XZ, Wang Yard, Ma YW (2017) High performance lithium-ion hybrid capacitors employing Atomic number 26iiiO4-graphene blended anode and activated carbon cathode. ACS Appl Mater Interfaces 9:17137–17145

    Google Scholar

  34. Li B, Sun ZH, Zhao Y, Zhang ZS (2019) Facile synthesis of three-dimensional carbon nanotube/Fe3O4 microspheres equally sulfur host for high performance lithium-sulfur batteries. Mater Lett 255:126529

    Article  CAS  Google Scholar

  35. Yu QH, Luo RJ, Bai XL, Yang WC, Lu Y, Hou XY, Peng T, Liu XM, Kim JK, Luo YS (2018) Rational pattern of double-confined Mn2Oiii/Due south@Al2Oiii nanocube cathodes for lithium-sulfur batteries. J Solid State Electrochem 22:849–858

    Commodity  CAS  Google Scholar

  36. Duan MT, Wu MR, Xue K, Bian ZX, Shi J, Guo XM, Cao F, Zhang JH, Kong QH, Zhang F (2021) Preparation of CoO/SnOtwo@NC/S composite as high-stability cathode material for lithium-sulfur batteries. Int J Miner Metall Mater 28:1647–1655

    Commodity  CAS  Google Scholar

  37. Qiao ZS, Zhou F, Zhang QF, Pei F, Zheng HF, Xu WJ, Liu PF, Ma YT, Xie QS, Wang LS, Fang Twoscore, Peng DL (2019) Chemisorption and electrocatalytic upshot from CoxSny alloy for loftier performance lithium sulfur batteries. Energy Storage Materials 23:62–71

    Article  Google Scholar

  38. Ji PH, Zeng TB, Hu XB, Xu YL, Zhou GP (2018) LiMn2O4 as strong polysulfides adsorption carrier for high performance lithium-sulfur batteries. Solid Land Ionics 315:52–58

    Article  CAS  Google Scholar

  39. Xu K, Liang X, Wang LL, Wang Y, Yun JF, Lord's day Y, Xiang HF (2021) Tri-functionalized polypropylene separator by rGO/MoO2 blended for high-operation lithium-sulfur batteries. Rare Met xl:2810–2818

    Commodity  CAS  Google Scholar

  40. Yang LW, Li Y, Wang Y, Li Q, Chen YX, Zhong BH, Guo XD, Wu ZG, Liu YX, Wang GK, Song Y, Xiang Westward, Zhong YJ (2021) Nitrogen-doped sheet VO2 modified separator to enhanced long-cycle performance lithium-sulfur battery. J Power Sources 501:230040

    Article  CAS  Google Scholar

  41. Tang TY, Zhang T, Zhao LN, Zhang B, Li Due west, Xu JJ, Li T, Zhang 50, Qiu HL, Hou YL (2020) Multifunctional FiveiiiSouthwardiv-nanowire/graphene composites for loftier performance Li-S batteries. Science China-Materials 63:1910–1919

    Article  CAS  Google Scholar

  42. Jiang SX, Chen MF, Wang XY, Zeng P, Li YF, Liu H, Li XL, Huang C, Shu HB, Luo ZG, Wu C (2019) A tin disulfide nanosheet wrapped with interconnected carbon nanotube networks for application of lithium sulfur batteries. Electrochim Acta 313:151–160

    Article  CAS  Google Scholar

  43. He JR, Hartmann Grand, Lee Chiliad, Hwang GS, Chen YF, Manthiram A (2019) Freestanding 1T MoStwo/graphene heterostructures as a highly efficient electrocatalyst for lithium polysulfides in Li-Due south batteries. Energy Environ Sci 12:344–350

    Commodity  CAS  Google Scholar

  44. Wang YQ, Xu Y, Ma SX, Duan RM, Zhao YF, Zhang YF, Liu ZH, Li C (2020) Depression temperature performance enhancement of high-safety lithium–sulfur battery enabled by synergetic adsorption and catalysis. Electrochim Acta 353:136470

    Article  CAS  Google Scholar

  45. Ma ZY, Liu Y, Gautam J, Liu WT, Chishti AN, Gu J, Yang G, Wu Z, Xie J, Chen One thousand, Ni LB, Diao GW (2021) Embedding cobalt atom clusters in CNT-wired MoS2 tube-in-tube nanostructures with enhanced sulfur immobilization and catalyzation for Li-S batteries. Small 17:2102710

    Article  CAS  Google Scholar

  46. Che B, Wang D, Xu 90 (2019) Southward@NiS Hollow spheres as cathode materials for lithium-sulfur batteries. Int J Electrochem Sci 14:9520–9526

    Commodity  CAS  Google Scholar

  47. Wang YK, Zhang RF, Dominicus ZH, Wu H, Lu SY, Wang JA, Yu West, Liu JM, Gao GX, Ding SJ (2020) Spontaneously formed Mott-Schottky electrocatalyst for lithium-sulfur batteries. Adv Mater Interfaces vii:1902092

    Commodity  CAS  Google Scholar

  48. Chen WM, Jin HC, Xie Due south, Xie HY, Zhu JF, Ji HX, Wan LJ (2021) TiN nanocrystal anchored on N-doped graphene as effective sulfur hosts for high-performance lithium-sulfur batteries. J Energy Chem 54:16–22

    Article  Google Scholar

  49. Cao YB, Wang CC, Wang XH, Zhang HJ, Jiang XM, Xiong CY, Liang F (2021) 2-dimensional mesoporous B, N co-doped carbon nanosheets decorated with Tin can nanostructures for enhanced performance lithium–sulfur batteries. Appl Phys A 127:933

    Commodity  CAS  Google Scholar

  50. Liu RQ, Liu WH, Bu YL, Yang WW, Wang C, Priest C, Liu ZW, Wang Y, Chen JY, Wang YH, Cheng J, Lin XJ, Feng XM, Wu G, Ma YW, Huang W (2020) Conductive porous laminated vanadium nitride as carbon-gratis hosts for high-loading sulfur cathodes in lithium-sulfur batteries. ACS Nano 14:17308–17320

    Commodity  CAS  Google Scholar

  51. Cheng ZZ, Wang YX, Zhang WJ, Xu M (2020) Boosting polysulfide conversion in lithium–sulfur batteries past cobalt-doped vanadium nitride microflowers. ACS Applied Energy Materials 3:4523–4530

    Commodity  CAS  Google Scholar

  52. Li North, Xu ZM, Wang P, Zhang ZA, Hong B, Li J, Lai YQ (2020) High-rate lithium-sulfur batteries enabled via vanadium nitride nanoparticle/3D porous graphene through regulating the polysulfides transformation. Chem Eng J 398:125432

    Article  CAS  Google Scholar

  53. Qiao L, Ren LT, Zhang RR, Chen J, Xu MG, Liu J, Xu HJ, Liu W, Chang Z, Sun XM (2021) Hollow carbon spheres embedded with VN quantum dots as an efficient cathode host for lithium–sulfur batteries. Energy Fuels 35:10219–10226

    Article  CAS  Google Scholar

  54. Deng DR, Xue F, Bai CD, Lei J, Yuan RM, Zheng MS, Dong QF (2018) Enhanced adsorptions to polysulfides on graphene-supported BN nanosheets with excellent Li-Due south battery functioning in a wide temperature range. ACS Nano 12:11120–11129

    Commodity  CAS  PubMed  Google Scholar

  55. Mussa Y, Bayhan Z, Althubaiti North, Arsalan M, Alsharaeh E (2021) Hexagonal boron nitride effect on the performance of graphene-based lithium–sulfur batteries and its stability at elevated temperatures. Mater Chem Phys 257:123807

    Commodity  CAS  Google Scholar

  56. He B, Li WC, Zhang Y, Yu XF, Zhang BS, Li F, Lu AH (2018) Paragenesis BN/CNTs hybrid as a monoclinic sulfur host for high rate and ultra-long life lithium–sulfur battery. J Mater Chem A 6:24194–24200

    Commodity  CAS  Google Scholar

  57. Li Southward, Xiang Q, Aslam MK, Cen Y, Guo C, Hu J, Li W, Chen C (2019) Atomic number 26-functionalized mesoporous carbonaceous microsphere with high sulfur loading equally cathode for lithium-sulfur batteries. J Electroanal Chem 850:113408

    Commodity  CAS  Google Scholar

  58. Gao Z, Schwab Y, Zhang YY, Song NN, Li XD (2018) Ferromagnetic nanoparticle-assisted polysulfide trapping for enhanced lithium-sulfur batteries. Adv Func Mater 28:1800563

    Article  Google Scholar

  59. Zhang H, Cui H, Li J, Liu Y, Yang Y, Wang M (2019) Frogspawn inspired hollow Iron3C@N-C every bit an efficient sulfur host for loftier-charge per unit lithium-sulfur batteries. Nanoscale eleven:21532–21541

    Commodity  CAS  PubMed  Google Scholar

  60. Jin ZS, Zhao 1000, Lin TN, Wang Z, Zhang Q, Liu BQ, Li L, Chen LH, Zhang LY, Su ZM, Wang CG (2020) Ordered micro-mesoporous carbon spheres embedded with well-dispersed ultrafine FethreeC nanocrystals as cathode material for high-performance lithium-sulfur batteries. Chem Eng J 388:124315

    Commodity  CAS  Google Scholar

  61. Lei WX, Wang XR, Zhang YW, Luo ZY, Xia PT, Zou YL, Ma ZS, Pan Y, Lin S (2021) Facile synthesis of Iron3C nano-particles/porous biochar cathode materials for lithium sulfur battery. J Blend Compd 853:157024

    Article  CAS  Google Scholar

  62. Zhao TK, Chen JW, Dai KQ, Zhang JX, Yuan ML, Li XQ, Zhang One thousand, Zhang JT, Li YL, Liu ZJ, He HY, Li B, Zhang GJ (2022) Boosted polysulfides regulation by iron carbide nanoparticles-embedded porous biomass-derived carbon toward superior lithium-sulfur batteries. J Colloid Interface Sci 605:129–137

    Commodity  CAS  PubMed  Google Scholar

  63. Zhao S, Wei ZB (2020) Novel starfish-like Mo2C framework as efficient sulfur host for high electrochemical performance lithium–sulfur batteries. J Chem Technol Biotechnol 96:249–253

    Article  Google Scholar

  64. Liu GL, Yuan C, Zeng P, Cheng C, Yan TR, Dai KH, Mao J, Zhang L (2022) Bidirectionally catalytic polysulfide conversion by high-conductive metal carbides for lithium-sulfur batteries. J Energy Chem 67:73–81

    Commodity  Google Scholar

  65. Wang JY, Wang WJ, Li HP, Tan TZ, Wang 10, Zhao Y (2019) Carbon nanotubes/SiC prepared past catalytic chemic vapor degradation every bit scaffold for improved lithium-sulfur batteries. J Nanopart Res 21:113

    Article  Google Scholar

  66. Shi NX, 11 BJ, Feng ZY, Liu JC, Wei DH, Liu J, Feng JK, Xiong SL (2019) Strongly coupled W2C atomic nanoclusters on N/P-codoped graphene for kinetically enhanced sulfur host. Adv Mater Interfaces half-dozen:1802088

    Article  Google Scholar

  67. Vu DL, Kim N, Myung Y, Yang M, Jw L (2020) Aluminum phosphate as a bifunctional additive for improved cycling stability of Li-South batteries. J Ability Sources 459:228068

    Commodity  CAS  Google Scholar

  68. Jin Y, Ji PH, Hu XB, Qi XQ, Li Chiliad, Lin ZJ (2022) VOPO4 as effective long-chain polysulfides adsorbent for lithium-sulfur batteries. Ionics 28:609–617

    Article  CAS  Google Scholar

  69. Li JF, Niu ZH, Chen YL, Zhou QH, Yan Y, Guo C, Li M (2020) Mn3(PO4)ii/rGO every bit dual-function polysulfide inhibitor through oxygen deficiencies and polar sites for lithium sulfur batteries. Appl Surf Sci 521:146425

    Article  CAS  Google Scholar

  70. Zhao W, Feng WJ, Chen JZ, Huang ZY (2022) ZIF-67-derived cobalt-based sulfate CoSO4/carbon nanotube nanocomposites as host textile for high-performance lithium-sulfur bombardment cathode. Ionics 28:635–645

    Article  CAS  Google Scholar

  71. Lu XL, Wang H, Liu XQ, Song ZC, Jiang Northward, Xie FY, Zheng QJ, Lin DM (2020) Functional separators prepared via in-situ growth of hollow CoSOfour hydrate arrays on pristine polypropylene membrane for high performance lithium-sulfur batteries. J Alloy Compd 838:155638

    Commodity  Google Scholar

Download references

Author data

Authors and Affiliations

  1. Primal Laboratory of New Processing Technology for Nonferrous Metal & Materials, Ministry of Education, Guangxi Key Laboratory of Optical and Electronic Materials and Devices, College of Materials Science and Engineering, Guilin Academy of Engineering science, Guilin, 541004, People'south Republic of Mainland china

    Jiangle Wang, Rui Du, Chuanbai Yu, Chengying Xu & Zhangyan Shi

Corresponding writer

Correspondence to Rui Du.

Additional information

Publisher'south Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor holds exclusive rights to this article nether a publishing understanding with the author(s) or other rightsholder(southward); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicative law.

Reprints and Permissions

Well-nigh this article

Verify currency and authenticity via CrossMark

Cite this article

Wang, J., Du, R., Yu, C. et al. Application of transition metal compounds in cathode materials for lithium-sulfur battery. Ionics (2022). https://doi.org/10.1007/s11581-022-04771-five

Download commendation

  • Received:

  • Revised:

  • Accustomed:

  • Published:

  • DOI : https://doi.org/10.1007/s11581-022-04771-5

Keywords

  • Transition metal compounds
  • Lithium-sulfur battery
  • Cathode materials
  • Electrochemical performance

Lithium And Sulfur Ionic Compound,

Source: https://link.springer.com/article/10.1007/s11581-022-04771-5

Posted by: broughtonthir1999.blogspot.com

0 Response to "Lithium And Sulfur Ionic Compound"

Post a Comment

Subscribe to: Post Comments (Atom)

Iklan Atas Artikel

Iklan Tengah Artikel 1

Iklan Tengah Artikel 2

Iklan Bawah Artikel